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<span style="font-size: 14px;"> 聯(lián)系人：邵猛 <br>電話(huà)：17366499126（微信同號） <br>郵箱：hy@ehuanya.com <br>地址：江蘇省通州灣江海聯(lián)動(dòng)開(kāi)發(fā)示范區東海大道88號</span><br></span></div> </div> </div> </div></div></div><style class="column_class qfy_style_class">@media only screen and (min-width: 992px){.qfy-column-1-5e1f0a004a990350895 > .column_inner {padding-left:0;padding-right:0;padding-top:11px;padding-bottom:0;}.qfe_row .vc_span_class.qfy-column-1-5e1f0a004a990350895 {};}@media only screen and (max-width: 992px){.qfy-column-1-5e1f0a004a990350895 > .column_inner{margin:0 auto 0 !important;min-height:0 !important;padding-left:0;padding-right:0;padding-top:0;padding-bottom:0;}.display_entire .qfe_row .vc_span_class.qfy-column-1-5e1f0a004a990350895 {}.qfy-column-1-5e1f0a004a990350895 > .column_inner> .background-overlay,.qfy-column-1-5e1f0a004a990350895 > .column_inner> .background-media{width:100% !important;left:0 !important;right:auto !important;}}</style><div data-animaleinbegin="bottom-in-view" data-animalename="qfyfadeInUp" data-duration="" data-delay="" class=" qfy-column-2-5e1f0a008a75c697103 qfy-column-inner vc_span_class vc_span9 text-Default small-screen-undefined notfullrow" data-dw="3/4" data-fixheight=""><div style="margin-top:0;margin-bottom:0;margin-left:0;margin-right:0;border-radius:0px;;position:relative;" class="column_inner "><div id="94ljdbk" class=" background-overlay grid-overlay-0" style="background-color:transparent;width:100%;"></div><div id="7fzb9x9" class="column_containter" style="z-index:3;position:relative;"> <div class="pfs94cp" id="vc_header_5e1f0a008ae83926" m-padding="0px 0px 20px 0px" p-padding="0 0 20px 0" css_animation_delay="0" qfyuuid="qfy_column_text_header_smrs7-c-9c" data-anitime="0.7" class="qfy-element minheigh1px qfe_text_column qfe_content_element " style="position: relative;;;background-repeat: no-repeat;;margin-top:0;margin-bottom:0;padding-top:0;padding-bottom:20px;padding-right:0;padding-left:0;"><style>@media only screen and (max-width: 768px) {#vc_header_5e1f0a008ae83926 .header_title{font-size:16px !important;}}@media only screen and (max-width: 768px) {#vc_header_5e1f0a008ae83926 .header_subtitle{font-size:20px !important;}}</style> <div id="tf94qgt" class="qfe_wrapper"> <h1 class="qfy_title left mobileleft"> <div id="qzoeyl9" class="qfy_title_inner" style="display:inline-block;position:relative;max-width:100%;"> <div id="xvecpus" class="header_title" style="font-family:微軟雅黑;font-size:26px;font-weight:normal;font-style:normal;color:#191919;"> 出水氨氮異常，有哪些迅速、有效的應急手段？ </div> </div> </h1> </div> </div> <div m-padding="0px 0px 0px 0px" p-padding="0 0 0 0" css_animation_delay="0" qfyuuid="qfy_column_text_mtoeb-c-9c" data-anitime="0.7" class="qfy-element qfy-text qfy-text-68107 qfe_text_column qfe_content_element newsdate " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:0;margin-bottom:20px;padding-top:0;padding-bottom:0;padding-right:0;padding-left:0;border-radius:0px;"> <div id="ukx44rt" class="qfe_wrapper"> <div><span style="" class="qfy_no_editor pdate">2022/9/5</span></div> </div> </div> <div m-padding="0px 0px 70px 0px" p-padding="0 0 70px 0" css_animation_delay="0" qfyuuid="qfy_column_text_re2wu-c-9c" data-anitime="0.7" data-ani_iteration_count="1" class="qfy-element qfy-text qfy-text-85363 qfe_text_column qfe_content_element " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:10px;margin-bottom:0;padding-top:0;padding-bottom:70px;padding-right:0;padding-left:0;border-radius:0px;"> <div id="chtgpnw" class="qfe_wrapper"> <p style="line-height: 2em;"><span style="font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); font-family: 微軟雅黑, "Microsoft YaHei";">在污水處理廠(chǎng)硝化系統出現問(wèn)題，出水氨氮超標時(shí)，想要迅速、有效的去除氨氮，只能通過(guò)物理化學(xué)的手段來(lái)應急了！常用且有效的物化手段目前只有折點(diǎn)加氯及沸石吸附法！市場(chǎng)上的很多氨氮去除劑就是次氯酸鹽，就是就是利用折點(diǎn)加氯的原理！</span></p><p style="line-height: 2em;"><span style="font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); font-family: 微軟雅黑, "Microsoft YaHei";"><br/></span></p><section><section><section><section><section><section><article><section><h2 style="margin: 0px 0px -1px; padding: 0px 5px 6px; outline: 0px; font-weight: 400; font-size: 16px; max-width: 100%; border-bottom: 2px solid rgb(204, 0, 0); display: inline-block; visibility: visible; line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); visibility: visible; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important; visibility: visible;"><span style="color: rgb(0, 0, 0); font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; visibility: visible; box-sizing: border-box !important; overflow-wrap: break-word !important;">1、折點(diǎn)加氯除氨氮</span></strong></span></h2></section></article></section></section></section></section></section></section><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; visibility: visible; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">折點(diǎn)加氯法是用化合價(jià)+1價(jià)氯的化合物次氯酸鈉（或者次氯酸鈣），把水體中的氨氮氧化為氮氣的加工工藝。當然還可以立即把氯氣進(jìn)入廢水中，運用歧化反應，生成次氯酸，隨后在將廢水中的NH3-N氧化成N2。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; visibility: visible; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">當氧化劑添加水里后，水里氨氮會(huì )被首要氧化成一氯銨，隨后會(huì )被繼續氧化變?yōu)槎劝?、三氯銨，三氯銨不穩定，會(huì )變?yōu)榈獨忉尫懦鰜?lái)，這就是折點(diǎn)加氯法的反映基本原理和過(guò)程，氨的濃度降為零。當氯氣進(jìn)入量超出該點(diǎn)時(shí)，水里的游離氯便會(huì )增加。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; visibility: visible; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">當添加的氧化劑做到足量時(shí)，水里的氨氮濃度最低標準（可是并非為零），同時(shí)水里余氯成分也是最低標準，超出這一點(diǎn)以后，水里余氯成分就剛開(kāi)始升高，因而該點(diǎn)稱(chēng)之為折點(diǎn)，該狀況下的氯化稱(chēng)之為折點(diǎn)氯化。但在實(shí)際生產(chǎn)中，應用折點(diǎn)加氯法往往存在折點(diǎn)、加氯量不好判斷的情況。</span></p><section><br/></section><section><section><section><section><section><section><article><section><h2 style="margin: 0px; padding: 0px; outline: 0px; font-weight: 400; font-size: 16px; max-width: 100%; line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(171, 25, 66); box-sizing: border-box !important; overflow-wrap: break-word !important;">1、加氯量-余氯曲線(xiàn)</span></strong></span></h2></section></article></section></section></section></section></section></section><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei";"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">看懂加氯量-余氯曲線(xiàn)，是用好折點(diǎn)加氯法的關(guān)鍵所在。</span><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">在水的加氯處理中，加氯量與余氯的關(guān)系如下圖所示。曲線(xiàn)的x軸和y軸分別代表加氯量和余氯量，單位為mg/l。其中，水中的加氯量可分為需氯量和余氯兩部分。如圖所示：</span></span></p></p><p style="line-height: 2em;"><img src="/admin888/ueditor/asp/upload/image/20220905/16623481298783506.png" title="image.png" alt="image.png"/></p><ul class=" list-paddingleft-2" style="padding: 0px 0px 0px 2.2em; outline: 0px; max-width: 100%; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><li><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">需氯量是指用于殺死細菌、氧化有機物和還原性物質(zhì)所消耗的部分。</span></p></li><li><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">余氯是指為了抑制水中殘余細菌的再度繁殖，尚需維持的少量氯。</span></p></li></ul><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">1、當水中無(wú)細菌、有機物和還原性物質(zhì)等，需氧量為零，加氯量等于余氯量，如圖中所示的虛線(xiàn)L1，該線(xiàn)與坐標軸成45度角。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">2、當水中含有細菌、有機物和還原性物質(zhì)，但主要不是游離氨時(shí)，需氧量OA滿(mǎn)足后就會(huì )出現余氯，如圖所示虛線(xiàn)L2，這條線(xiàn)與x軸交角小于45度，其原因為：</span></p></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"></span></p><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 16px; box-sizing: border-box !important; overflow-wrap: break-word !important;"></span><ul class=" list-paddingleft-2" style="padding: 0px 0px 0px 2.2em; outline: 0px; max-width: 100%; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><li><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px; box-sizing: border-box !important; overflow-wrap: break-word !important;">水中有機物與氯作用的速度有快慢。在測定余氯時(shí)，有一部分有機物尚在繼續與氯作用中。</span></p><section><br/></section></li><li><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px; box-sizing: border-box !important; overflow-wrap: break-word !important;">水中余氯有一部分會(huì )自行分解，如次氯酸由于受水中某些雜質(zhì)或光線(xiàn)的作用，產(chǎn)生如下的催化分解：2HOCl=2HCl+O2。</span></p><p style="text-align: left; line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;"><span style="font-size: 14px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"></span><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 15px; letter-spacing: 2px;">3、當水中的有機物主要是氨和氮化合物，情況比較復雜。</span></span></p></li></ul></section><p style="line-height: 2em;"><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">當起始的需氧量OA滿(mǎn)足后，加氯量增加，剩余氯也增加（曲線(xiàn)AH段），但后者增長(cháng)得慢一些。超過(guò)H點(diǎn)加氯量后，雖然加氯量增加，余氯量反而下降，如HB段，H點(diǎn)稱(chēng)為峰點(diǎn)。此后隨著(zhù)加氯量的增加，剩余氯又上市，如BC段，B點(diǎn)稱(chēng)為折點(diǎn)。</span></p><br/></p><p style="line-height: 2em;"><img src="/admin888/ueditor/asp/upload/image/20220905/16623481468244078.png" title="image.png" alt="image.png"/></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">a、在曲線(xiàn)OA段，表示水中雜質(zhì)把氯消耗光，余氯量為零，需氯量為b，這時(shí)雖然也能殺死一些細菌，但消毒效果不可靠。</span></p><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">b、在曲線(xiàn)AH段，加氯后，氯與氨發(fā)生反應，有余氯存在，所以有一定消毒效果，但余氯為化合性，其主要成分是一氯氨。氯和氨發(fā)生如下反應：NH3+HClO=NH2Cl+H2O。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">此時(shí)隨著(zhù)加氯量的增加，化合氯成比例增加，水中氨氮逐漸減少，當加氯量達到H點(diǎn)時(shí)，水中的氨降至零，化合性余氯升至最高。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">c、在曲線(xiàn)HB段，仍然產(chǎn)生化合性余氯，加氯量繼續增加，會(huì )發(fā)生如下反應：2NH2Cl+HClO=N2↑+H2O+3HCl。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">反應結果使氯胺被氧化成一些不起消毒作用的化合物，余氯量反而逐漸減少，最后到達折點(diǎn)B。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">d、在曲線(xiàn)BC段，超過(guò)折點(diǎn)B后，已經(jīng)沒(méi)有消耗氯的雜質(zhì)了，出現自由性余氯，該段消毒效果最好。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">由此可見(jiàn)水中含有氨氮時(shí)，加氯量-余氯曲線(xiàn)是一條折線(xiàn)，此時(shí)對應的加氯法稱(chēng)為折線(xiàn)加氯法。</span></p><section><br/></section><section><section><section><section><section><section><article><section><h2 style="margin: 0px; padding: 0px; outline: 0px; font-weight: 400; font-size: 16px; max-width: 100%; line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(171, 25, 66); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="color: rgb(171, 25, 66); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; box-sizing: border-box !important; overflow-wrap: break-word !important;">2、氨氮含量與加氯量、加氯點(diǎn)的關(guān)系</span></strong></span></h2></section></article></section></section></section></section></section></section><p style="line-height: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei";"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">一般情況下, 當 pH值在7左右, 采用折點(diǎn)加氯時(shí)，一氯胺、二氯胺、三氯胺同時(shí)存在。其中，產(chǎn)生的化合余氯成分以一氯胺為主，二氯胺和三氯胺少量存在（不影響分析），</span><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">因此，在實(shí)踐操作中為簡(jiǎn)化分析計算，常常將化合余氯看作一氯胺。</span></span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">假設水中雜質(zhì)的耗氧量為b（mg/l），即曲線(xiàn)OA段的耗氧量為b（mg/l），水中余氯控制目標值為a（mg/l）。</span></p><section><br/></section></p><p style="line-height: 2em;"><img src="/admin888/ueditor/asp/upload/image/20220905/16623481686343168.png" title="image.png" alt="image.png"/></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">如水中含無(wú)氨氮，采用游離加氯法。當加氯點(diǎn)為Y時(shí)（如圖所示），所需加氯量y=b+1.35a（mg/l）。</span></p><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">如水中含有c（mg/l）氨氮，采用折點(diǎn)加氯法，加氯量需分情況討論：</span></p><section><br/></section><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">1、當加氯點(diǎn)被控制在A(yíng)H段的Y1時(shí)，所需加氯量y1=b+1.38a（mg/l）。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">需要說(shuō)明的是，為確保加氯點(diǎn)能被控制在A(yíng)H段的Y1點(diǎn)，水中氨的含量必須滿(mǎn)足條件：c不小于0.33a（mg/l）。</span></p></p><p style="line-height: 2em;"><img src="/admin888/ueditor/asp/upload/image/20220905/16623481817174833.png" title="image.png" alt="image.png"/></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">2、當加氯點(diǎn)被控制在HB段的Y2點(diǎn)時(shí)，所需加氯量y2=b+4.18c+1.034*(3.03c-a)（mg/l）。</span></p><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">需要說(shuō)明的是，加氯點(diǎn)被控制在HB段的Y2點(diǎn)，在A(yíng)H段氨與氯氣反應，水中的氨全部被消耗掉。</span></p><section><br/></section><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">3、當加氯點(diǎn)被控制在BC段的Y3點(diǎn)時(shí)，所需加氯量y3=b+7.31c+1.35a（mg/l）。</span></p><section><br/></section></p><p style="line-height: 2em;"><img src="/admin888/ueditor/asp/upload/image/20220905/16623481966115888.png" title="image.png" alt="image.png"/></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">綜上所述，加氯量的大小與水中的雜質(zhì)含量、氨氮含量、余氯的控制目標值和所選擇的加氯點(diǎn)有關(guān)。</span></p><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">當水中雜質(zhì)含量一定，余氯的控制目標相同時(shí)，水中無(wú)氨氮時(shí)的加氯量要比有氨氮時(shí)的加氯量低，也就是說(shuō)氨氮會(huì )引起加氯量的增加，增加量主要取決于加氯點(diǎn)的位置。 </span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">如果水中含有氨氮，就采用折點(diǎn)加氯，從余氯-加氯量曲線(xiàn)可知，對應同一個(gè)余氯值，可能存在三個(gè)不同的加氯點(diǎn)，這三個(gè)加氯點(diǎn)分別對應的加氯量有很大差別。 </span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">實(shí)踐表明，在曲線(xiàn)BC段Y3點(diǎn)采用游離氯消毒的加氯量，要遠遠大于在A(yíng)H和HB段Y1、Y2點(diǎn)采用化合氯消毒的加氯量。 </span></p><section><br/></section></p><p style="line-height: 2em;"><img src="/admin888/ueditor/asp/upload/image/20220905/16623482076683882.png" title="image.png" alt="image.png"/></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">通常Y3點(diǎn)的加氯量可達到Y1點(diǎn)加氯量的2～3倍，為減少加氯量，折點(diǎn)加氯時(shí)的加氯點(diǎn)應選擇在加氯量-余氯曲線(xiàn)的AH段，此時(shí)的余氯是化合氯。</span></p><p><section><br/></section><section><section><section><section><section><section><article><section><h2 style="margin: 0px 0px -1px; padding: 0px 5px 6px; outline: 0px; font-weight: 400; font-size: 16px; max-width: 100%; border-bottom: 2px solid rgb(204, 0, 0); display: inline-block; line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="color: rgb(0, 0, 0); font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; box-sizing: border-box !important; overflow-wrap: break-word !important;">2、沸石吸附法除氨氮</span></strong></span></h2></section></article></section></section></section></section></section></section></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">沸石對氨氮的去除以物理吸附作用與離子交換作用為主，其吸附作用具有“快速吸附，緩慢平衡”的特點(diǎn)。</span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(171, 25, 66); font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="color: rgb(171, 25, 66); font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">1、吸附作用</span></strong></span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">在沸石的組成結構中，[SiO4]和[AlO4]以共角頂的形式聯(lián)成硅鋁氧格架，在格架中形成了許多寬闊的孔穴和孔道（占晶體總體積的50%以上），使得天然沸石具有比表面積大(通常在440～1030m2/g) ；天然沸石往往孔徑均勻，因而可以產(chǎn)生“超孔效應”；在沸石表面所具有的強大色散力作用下,沸石孔穴中分布的陽(yáng)離子和部分架氧所具有的負電荷相互平衡，使得沸石又具有較強的色散力和靜電力作用；加之沸石所特有的分子結構而形成的較大靜電引力，使沸石具有相當大的引力場(chǎng)，由以上四種因素的綜合作用使得沸石具有很強的吸附性，與其他吸附劑相比，沸石具有吸附量大、高選擇性和高效吸附等特點(diǎn)。</span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-family: 微軟雅黑, "Microsoft YaHei";"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; color: rgb(171, 25, 66); box-sizing: border-box !important; overflow-wrap: break-word !important;">2、離子交換作用</span></strong></span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">離子交換是指沸石晶體內部陽(yáng)離子與廢水中 NH4+ 進(jìn)行交換的化學(xué)過(guò)程：在硅(鋁) 氧四面體基本單元中，部分氧原子的價(jià)鍵未得到中和，使整個(gè)四面體基本單元帶有部分的負電荷，為達到電性中和，該四面體基本單元中缺少的正電荷會(huì )由附近帶正電的金屬離子陽(yáng)離子（如 K+、Na+、Ca2+、Mg2+）來(lái)補償；廢水中的 NH4+ 直徑小于沸石的孔穴通道直徑，通過(guò)沸石的吸附作用容易進(jìn)入孔穴到達沸石表面,并與沸石晶格中金屬離子陽(yáng)離子發(fā)生交換并將其置換下來(lái)，而且離子交換后的沸石并不發(fā)生結構變化，這使沸石具有離子交換特性。廢水中 NH4+ 與沸石中金屬離子陽(yáng)離子發(fā)生交換反應，使廢水中 NH4+ 減少，從而實(shí)現沸石對氨氮的去除作用。</span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(171, 25, 66); font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="color: rgb(171, 25, 66); font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">3、吸附作用影響因素</span></strong></span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-family: 微軟雅黑, "Microsoft YaHei";"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">1、沸石投加量及沸石粒徑對氨氮去除效果的影響</span></strong></span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">在一定范圍內，沸石用量增加，NH4-N 去除率也增加。但并非用量越多去除效果越好，有研究表明：沸石用量在 2g/L 以上時(shí)，去除效果并未明顯增加，另外再增加沸石用量從經(jīng)濟角度也是不科學(xué)的。楊勝科等研究發(fā)現：1g 沸石就可以將 200mL 水樣中1mg/L NH4+ 降至 0.2mg/L 以下,此時(shí)已低于國家飲用水標準，再增加沸石用量，并未顯著(zhù)地提高 NH4+ 的去除率，相反卻使水質(zhì)產(chǎn)生渾濁，從而影響水體的渾濁度指標，并易使比色測定誤差增大，為此針對不同成分的含氨氮水，應將沸石用量控制在一定的范圍內。</span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-family: 微軟雅黑, "Microsoft YaHei";"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">2、溫度對氨氮去除效果的影響</span></strong></span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">沸石對氨氮的去除效果與廢水的溫度有著(zhù)密切關(guān)系：隨著(zhù)溫</span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">度升高,沸石對氨氮的吸附能力加強,因為溫度的升高,使得 NH4+ 離子動(dòng)能增加, 運動(dòng)頻率也隨之增加, 運動(dòng)頻率較高的 NH4+ 離子更容易深入到沸石空穴中而被交換吸附。</span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-family: 微軟雅黑, "Microsoft YaHei";"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">3、pH 對氨氮去除效果的影響</span></strong></span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(34, 34, 34); font-family: system-ui, -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 2em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 15px; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">沸石對氨氮的去除隨廢水 pH 值的增加而先增大后減小[7]：當溶液偏酸性時(shí)，溶液中存在大量的 H+，H+ 的半徑要遠小 NH4+ 的半徑, 比 NH4+ 更容易與沸石上的金屬陽(yáng)離子發(fā)生交換，不利于 NH4+ 的交換；當溶液偏堿性時(shí)，OH- 與 NH4+ 發(fā)生中和反應，生成 NH3，使得水中氨氮以分子形態(tài)存在, NH3 不能與沸石進(jìn)行離子交換，僅吸附現象起作用,氨氮去除能力下降。</span></p><p><br/></p> </div> </div> <div style="margin-top:0;margin-bottom:0;padding-top:0;padding-bottom:0;padding-right:0;padding-left:0;" m-padding="0px 0px 0px 0px" p-padding="0 0 0 0" css_animation_delay="0" qfyuuid="qfy_prenext_tq83q-c-9c" class="qfy-prenext qfy-element normallayout borderrightnone vcprenext-5e1f0a008bd1d5048"> <style> .lrlayout .prenext_inner .action{display:inline;} .lrlayout .prenext_inner .title{display:inline-block;} .lrlayout .prenext_inner .pre_inner{vertical-align: middle;} body .lrlayout .blank{display:block;} .lrlayout .pre_a{float:left;} .lrlayout .next_a{float:right;} .lrmiddlelayout .prenext_inner .action{display:none;} .lrmiddlelayout .prenext_inner .title{display:inline-block;} .lrmiddlelayout .prenext_inner .pre_inner{vertical-align: middle;} .lrmiddlelayout .blank{display:block;} .lrmiddlelayout .pre_a{float:left;position:relative;} .lrmiddlelayout .next_a{float:right;position:relative;} .lrmiddlelayout .pre_a 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